Research Group: Photochemical Oxidation Products

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Specific scientific questions of current interest

  • How well is OH production and loss understood particularly in unique environments such as Antarctica and anthropogenic plumes?
  • What are the remote marine oxidants responsible for the formation of gas phase sulfuric and methanesulfonic acids and DMSO at night?
  • How do MS/sulfate ratios observed in the Antarctic ice depend on DMS oxidation chemistry and transport over the polar plateau?
  • What are the primary chemical compounds responsible for nucleation and growth?
  • Does ammonia have a unique role in controlling particle growth?
  • Why does nucleation observed in the lower troposphere occur at a much lower concentration and with a weaker functional dependence on H2SO4 than predicted by classical theory?
  • What is the role of particles formed by nucleation in cloud processes and climate?

New Research Thrusts

  • Development of an aircraft based ammonia measurement capability
  • Characterize the chemical composition of ambient ultrafine aerosols. Of particular of interest are insoluble organic species
  • Develop new chemical ionization ion trap mass spectrometric measurement technique for a broad range of oxygenated biogenic and anthropogenic compounds